FISHER SCIENTIFIC -- ZINC NITRATE  -- 6810-00N050581
<pre>=====================  Product Identification  =====================

Product ID:ZINC NITRATE
MSDS Date:06/17/1993
FSC:6810
NIIN:00N050581
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company Name:FISHER SCIENTIFIC CO.  CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 24:W/FULL FACEPIECE OPERATED IN PRESS-DEMAND OR OTHER
    POS PRESS MODE.
RTECS #:9999999ZZ

Ingred Name:ING 23:DEMAND/OTHER POS PRESS MODE OR W/FULL FACEPIECE,
    HELMET/HOOD OPERATED IN CONTINUOUS-FLOW MODE. ANY SCBA (ING 25)
RTECS #:9999999ZZ

Ingred Name:ING 10:IMMED. INGEST:DILUTE POIS IMMED W/LG AMTS OF
    WATER/MILK & REMOVE BY GASTRIC LAVAGE UNLESS VICTIM IS (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:ALREADY VOMIT. GET MED ATTN IMMED. ADMIN OF GASTRIC
    LAVAGE SHOULD BE PERFORMED BY QUALIFIED MED PERS. (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12:ANTIDOTE:DECISION AS TO WHETHER SEVERITY OF POIS
    REQS ADMIN OF ANY ANTIDOTE & ACTUAL DOSE REQD SHOULD BE (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:MADE BY QUALIFIED MED PERS. GIVE CALCIUM DISODIUM
    EDETATE 15-25 MG/KG (0.08-0.125 ML OF 20% SOLN/KG OF (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:BODY WT) IN 250-500 ML OF 5% DEXTROSE IV OVER 1-2 HR
    PERIOD TWICE DAILY. MAX DOSE SHOULD NOT EXCEED 50 (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:MG/KG/DAY. DRUG SHOULD BE GIVEN IN 5-DAY COURSES
    W/REST PERIOD OF AT LST 2 DAYS BTWN COURSES. AFTER FIRST(ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:COURSE, SUBSEQUENT COURSES SHOULD NOT EXCEED 50
    MG/KG/DAY. DAILY URINALYSES SHOULD BE DONE DURING (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:TREATMENT PERIOD. DOSAGE SHOULD BE REDUCED IF ANY
    UNUSUAL URINARY FINDINGS APPEAR. FOR INTRAMUSCULAR (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:ADMIN, GIVE 12.5 MG/KG BODY WT EVERY 4-6 HRS. DILUTE
    EACH DOSE W/EQUAL VOL OF 1% PROCAINE. DOSE (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:LIMITATION IS SAME AS THAT GIVEN ABOVE. ANTIDOTE
    SHOULD BE ADMINISTERED BY QUALIFIED MED PERS.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP.
    FOR LGR SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21:DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZARD AREA &
    DENY ENTRY. RQ:1000 LBS.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:EFFICIENCY PARTICULATE FILTER; ANY TYPE 'C'
    SUPPLIED-AIR RESP W/FULL FACEPIECE OPERATED IN PRESS- (ING 24)
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:OCCAS LIFTING UPPER & LOWER LIDS, UNTIL NO
    EVID OF CHEM REMAINS (APPROX 15-20 MINS). GET MED ATTN(ING 11)
RTECS #:9999999ZZ

Ingred Name:ZINC NITRATE  (SARA III)
CAS:7779-88-6
RTECS #:ZH4772000
Fraction by Wt: 100%
OSHA PEL:N/K 
ACGIH TLV:N/K 
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:EXPLO HAZ:MATTER. CONT W/EASILY OXIDIZABLE, ORG/OTHER
    COMBUST MATLS MAY RSLT IN IGNIT, VIOLENT COMBUST/EXPLO.
RTECS #:9999999ZZ

Ingred Name:MATLS TO AVOID:STANNOUS CHLORIDE, THIOCYANATES, ALUMINUM,
    CITRIC ACID, ESTERS, PHOSPHINATES, POTASSIUM (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:HEXANITROCOBALTATE(3-), REDUCTANTS, TIN(II) CHLORIDE.
RTECS #:9999999ZZ

Ingred Name:EFTS OF OVEREXP:DIARR, SHOCK, COLLAPSE & POSS DEATH.
    SURVIVORS MAY HAVE RESIDUAL NEPHRITIS & STRICTURES OF (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:ESOPHAGUS & PYLORIC END OF STOM. RARELY, INORG
    NITRATES MAY BE CONVERTED TO NITRITES BY NITRATE-REDUCING (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:BACTERIA IN UPPER DIGEST TRACT, RSLTG IN
    METHOMOGLOBINEMIA. CHRONIC:SKIN:MAY CAUSE DERM/GRANULOMA. EYE: (ING
    8)
RTECS #:9999999ZZ

Ingred Name:ING 7:EXPOS TO IRRITS MAY CAUSE CONJ. INGEST:RPTD ORAL
    ADMIN OF SM DOSES OF ZINC SALTS MAY CAUSE DIGEST (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:DISORDERS & CONSTIP. RPTD & PRLNG EXPOS TO NITRATES
    MAY CAUSE ANEMIA, NEPHRITIS & POSS METHEMOGLOBINEMIA.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL, RAT) 1190 MG/KG.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:DUST MAY CAUSE IRRIT OF
    NOSE & THROAT, COUGH, LABORED BRTHG & POSS LUNG EDEMA. SKIN:CONT
    MAY CAUSE IRRIT W/REDNESS, PAIN & POSS BURNS. APPLICATION OF 500 MG
    OF HEXAHYDRATE TO RABBITS FOR 2 4 HRS RSLTD IN SEV IRRIT.
    ABSORPTION MAY OCCUR. EYE:CONT MAY CAUSE POSS DELAYED IRRIT
    W/REDNESS, TEARS,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:PAIN & BLURRED VISION. APPLICATION OF
    20 MG OF HEXAHYDRATE TO RABBITS FOR 24 HRS RSLTD IN MOD IRRIT.
    INGEST:MAY CAUSE SORE THROAT, METALLIC TASTE, GASTRIC IRRIT & PAIN,
    FAINTNESS, NAUS, VOMIT , CRAMPS & BLUISH LIPS & SKIN. ZINC SALTS
    MAY CAUSE SUBSTERNAL PAIN & FEVER. SOLNS OF ZINC SALTS MAY ALSO
    CAUSE (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. IF BRTHG HAS
    STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & AT REST. TREAT
    SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN:REMOVE
    CONTAM CLTHG &  SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD
    DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (APPROX
    15-20 MINS). GET MED ATTN IMMED. EYE:WASH IMMED W/LG AMTS OF
    WATER/NORM SALINE, (ING 10)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:WATER ONLY. NO DRY CHEMICAL, CARBON DIOXIDE OR
    HALON. FOR LARGER FIRES, FLOOD AREA W/WATER FROM A DISTANCE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
    MOVE CNTNR FROM FIRE AREA IF YOU CAN DO IT W/OUT RISK. APPLY
    COOLING WATER TO SIDES OF CNTNRS EXPOS(SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOS TO HEAT/FLAME.
    OXIDIZERS DECOMPOSE, ESP WHEN HEATED, TO YIELD OXYGEN/OTHER GASES
    WHICH WILL INCR BURNING RATE OF COMBUST (ING 2)

==================  Accidental Release Measures  ==================

Spill Release Procedures:KEEP COMBUSTS(WOOD, PAPER, OIL, ETC) AWAY FROM
    SPILLED MATL. DO NOT TOUCH SPILLED MATL. FOR SM DRY SPILLS, W/CLEAN
    SHOVEL PLACE MATL INTO CLEAN, DRY CNTNR & COVER. MOVE CNTNRS FROM
    SPILL AREA. FOR SM	LIQ SPILLS, TAKE UP W/SAND, EARTH/OTHER(ING 21)
Neutralizing Agent:NEUT W/AGRICULTURAL LIME, SLAKED LIME, CRUSHED
    LIMESTONE/SODIUM BICARBONATE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:OBSERVE ALL FED, STATE & LOC REGS WHEN
    STORING THIS SUBSTANCE. STORE IN COOL, DRY PLACE, KEEP CNTNR
    TIGHTLY CLSD WHEN NOT IN USE.
Other Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES. CONSULT NFPA
    PUBLICATION 43A, STORAGE OF LIQ & SOLID OXIDIZING MATLS, FOR
    STORAGE REQUIREMENTS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:SPECIFIC RESP SELECTED MUST BE NIOSH/MSHA
    APPRVD: ANY DUST & MIST RESP W/FULL FACEPIECE; ANY AIR PURIFYING
    FULL FACEPIECE RESP W/HIGH-EFFICIENCY PARTICULATE FILTER; ANY
    POWERED AIR-PURIFYING RESP W/TI GHT-FITTING FACEPIECE & HIGH- (ING
    23)
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION
    SYSTEM.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPVD SPLSH PRF DUST (OTR PROT EQPT
Other Protective Equipment:APPROP PROT (IMPERV) CLTHG & EQUIP. EYEWSH
    FNTN W/IN IMMED WORK AREA FOR EMERG USE.EYE PROT: RESIS GOGG 
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:TO FLAMES UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE
    FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZS. IF THIS
    IS IMPOSS, W/DRAW FROM AREA & LET FIRE BURN. FLOOD W/WATER. COOL 
    CNTNRS W/FLOODING AMTS OF WATER. APPLYFROM AS FAR DIST AS POSS.
    EVACUATE TO RADIUS OF 2500 FT FOR UNCONTROLLABLE FIRE.

==================  Physical/Chemical Properties  ==================

Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS TO WHITE VERY HYGROSCOPIC CRYSTALS
    W/ASTRIGENT TASTE; ODORLESS.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
CARBON, COMBUST MATLS, CYANIDES, METALS(PWDR), ORG MATLS, PHOSPHOROUS,
    REDUCING MATLS, SODIUM HYPOPHOSPHATE, (ING 3)
Stability Condition to Avoid:AVOID CONT W/COMBUST MATLS (WOOD, PAPER,
    FUEL, OILS, ETC), IGNIT/EXPLO MAY RSLT. AVOID CONTAM OF WATER
    SOURCES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
    INCLUDE TOXIC OXIDES OF NITROGEN & ZINC.

====================  Disposal Considerations  ====================

Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
    WHEN DISPOSING OF THIS SUBSTANCE.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.'