PRAXAIR INC -- ARGON -- 6685-00-292-1189
===================== Product Identification ===================== Product ID:ARGON MSDS Date:12/01/1992 FSC:6685 NIIN:00-292-1189 === Responsible Party === Company Name:PRAXAIR INC Address:39 OLD RIDGEBURY RD City:DANBURY State:CT ZIP:06817-0001 Country:US Info Phone Num:203-794-5782 Emergency Phone Num:203-794-5782/800-424-9300(CHEMTREC) CAGE:0LV01 === Contractor Identification === Company Name:MOELLER INSTRUMENT CO Address:126 MAIN ST Box:668 City:IVORYTON State:CT ZIP:06442 Country:US Phone:860-767-2104 CAGE:76526 Company Name:PRAXAIR, INC. Address:39 OLD RIDGEBURY RD Box:City:DANBURY State:CT ZIP:06810-5113 Country:US Phone:800-772-9247; 800-PRAXAIR CAGE:0LV01 ============= Composition/Information on Ingredients ============= Ingred Name:ARGON CAS:7440-37-1 RTECS #:CF2300000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:TLV:SIMPLE ASPHYXIANT, 0.5MG/M3 Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INGEST:PROD GAS @NORMAL TEMP/PRESSURE.SKIN ABSORP:NO EVIDENCE OF ADVERSE EFFECTS FRM AVAI INFO.INHAL:ASPHYXIANT.MODERATE CONC MAY CAUSE HEAD,DROWS,DIZZ,EXCITATION,EXCESS SALIVATION,VOMIT,UNCONSC.SKIN/ EYE:NO HARMFUL EFFECT EXPECTED FRM VAP.CHRONIC:NO EVIDENCE OF ADVERSE EFFECTS FRM AVAI INFO.WORKING W/WELD/CUT MAY (SUP) Effects of Overexposure:ARGON AN ASPHYXIANT.LACK OF OXYGEN CAN CAUSE DEATH. SHORT TERM OVEREXPO TO WELD/CUT FUMES MAY RESULT IN DISCOMFORT SUCH AS DIZZ,NAU,DRYNESS OR IRRIT OF NOSE/THROAT/EYES. Medical Cond Aggravated by Exposure:A KNOWLEDGE OF AVAI TOXICLOLOGY INFO & OF PHYS/CHEM PROPERTIES OF MATL SUGGEST THAT OVEREXPO IS UNLIKELY TO AGGRAVATE EXISTING MED CONDITIONS. ======================= First Aid Measures ======================= First Aid:INGEST:PRODU GAS @NORMAL TEMP/PRESSURE.SKIN:FLUSH W/ATER.INHAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL RESP IF NOT BREATHING.GIVE OXYGEN IF BREATHING IS DIFFICULT.CALL PHYSICIAN.EYE:FLUSH W/WATER.NOTE TO DR:PRODUCT IS INERT.THERES NO SPECIFIC ANTIDOTE.TREATMENT OF OVEREXPO SHOULD BE DIRECTED @CONTROL OF SYMPTOMS & CLINICAL CONDITIONS. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:NA Lower Limits:N/APPLICABLE Upper Limits:N/APPLICABLE Extinguishing Media:ARGON CANNOT CATCH FIRE.USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:EVACUATE ALL PERSON FRM DANGER AREA.IMMED COOL CNTNR W/WATERSPRAY FRM MAX DISTANCE TIL COOL,THEN MOVE CNTNR AWAY FROM FIRE AREA W/O RISK.SHUT OFF LEAD W/O RISK. Unusual Fire/Explosion Hazard:ARCS/SPARK IGN COMBUST.REF:ANSZ49.1.CNTNR MAY RUPTURE DUE TO FIRE HEAT.NO PART OF CNTNR SHOULD BE SUBJ TO TEMP >52C.MOST CNNTR PROVIDED W/PRESUSE RELIEF(SUPPLE) ================== Accidental Release Measures ================== Spill Release Procedures:ARGON ASPHYXIANT.EVACUATE ALL PERSON.USE SCBA WHERE NEEDED.SHUT OFF CYL W/O RISK.VENTI AREA OR MOVE CYL TO WELL VENTI AREA.TEST AREA ESPEC CONF AREA FOR SUFFI OXY CONTENT PRIOT TO RE-ENTRY OF PERSONNE L. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:ARC/SPARK DURING USE COULD IGN SOURCE FOR COMBUST MATL.PREVENT FIRES.SEE NFPA 51B.USE PIPING/EQPMT ADEQUATE DESIGNED TO W/STAND PRESSURES ENCOUNTERED. Other Precautions:GAS CAN CAUSE RAPID SUFFOCATION-OXY DEFFIC.STORE/USE W/ADEQUATE VENTI.DONT ALLOW CYL TO BECOME PART OF ELECTR CIRCUIT.READ/UNDERSTAND MFG INSGTRUCTIONS/PRECAUT LABEL.FUME/GAS CANT BE CLASSIFIED SIMPLY -DEPENDS ON METAL,CONDITIONS,WORKER,ETC. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE AIR-PURIF/AIR-SUPP RESP AS APPROPR WHERE LOC &/OR GEN EXHAU VENTI NOT ADEQUATE TO KEEP WORKER EXPO BEL APPLICABLE TLV DURING WELD OPERATIONS W/ARGON.AIR SUPP RESP REQUIRE WHILE WORK IN CONF SPACES .CONFORM RESP PROT USE W/29CFR1910.134. Ventilation:LOC EXHAU-USE IF NECESASRY TO MAINTAIN HAZ FUMES/GAS CONCE BEL APPLICABLE TLV IN WORK BREATH ZONE.MECH(GEN)-UNDER (SUPP) Protective Gloves:WELDING GLOVES RECOMMENDED Eye Protection:HELMET,FACESHIELD W/FILT PER ANSI Z49.1 Other Protective Equipment:PROVIDE PROT SCREEN/FLASH GOGG IF NECESSARY TO PROT OTHER.SELECT PER 29CFR1910.133.HAND/HEAD/BODY PROT AS NEED.DK CLOTH. Work Hygienic Practices:SEE OSHA PUBLICATION 2206(29CFR1910) & PRAXAIR PUBLICATION L-52-529.NEVER WORK ON PRESSURIZED SYSTEM. Supplemental Safety and Health FIRE/EXPLO:DEVICE DESIGNED TO VENT CONTENTS WHEN EXPO TO ELEV TEMP. HEALTH:CREATE ADDN HEALTH HAZ.FUMES/GASES CAN BE DANGEROUS,MAY CAUSE SERIOUS LUNG DISEASES. CONDITIONS AVOID:DONT STRIKE ARC ON CYL. DONT GROUND CYL. VENTI:CERTAIN WORK CONDITIONS GENE EXHAU VENTI MAY BE ACCEPTABLE PROVIDE THAT ADEQEQ TO MAINT BEL TLV. ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:-301F,-185C Melt/Freeze Pt:M.P/F.P Text:-309F,-189C Decomp Temp:Decomp Text:NP Vapor Pres:GAS Vapor Density:1.378 @21C Spec Gravity:GAS pH:NP Viscosity:NP Solubility in Water:NEGLIGIBLE Appearance and Odor:COLORLESS,ODORLESS GAS AT NORMAL TEMP & PRESSURE Percent Volatiles by Volume:100 Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE CURRENTLY KNOWN. ARGON IS CHEMICALLY INERT. Stability Condition to Avoid:HI PRESSURE GAS.CLOSE VALVE WHEN NOT IN USE/EMPTY.USE W/EQPMT RATED TO ADEQUATELY W/STAND PRESSREU TO BE ENCOUNTERE(SUP) Hazardous Decomposition Products:OZONE/NITROGEN OXIDES-FORM BY RADIATION FRM ARC.OTHER OF NORM OPERATION FRM VOLATILIZATION,REACTION OR OXIDATION OF MATL ==================== Disposal Considerations ==================== Waste Disposal Methods:SLOWLY RELEASE INTO ATM.DISCARD ANY PRODUCT,RESIDUE,DISPOSABLE CNTNR OR LINER IN ENVIRONMENTALLY ACCEPTABLE MANNER IN FULL COMPLIANCE W/FED/STATE/LOC REGS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.