Material Safety Data Sheet
    Iron Oxide
ACC# 09765
  
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Section 1 - Chemical Product and Company Identification | 
  
MSDS Name: Iron Oxide
Catalog Numbers:
     S80011, S93244, I119 500, I119-500, I119500, NC9073492, S76771
Synonyms:
     Black Iron Oxide; Magnetite; Triirion Tetroxide; Ferric(ous) Oxide..
Company Identification:
 
 
 
 
 
 
 
Fisher Scientific
 
 
 
 
 
 
 
1 Reagent Lane
 
 
 
 
 
 
 
Fair Lawn, NJ  07410
For information, call:  201-796-7100
Emergency Number:       201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
  
    | 
Section 2 - Composition, Information on Ingredients
 | 
  | CAS# | 
    Chemical Name | 
    Percent | 
    EINECS/ELINCS | 
|    1317-61-9 | 
IRON OXIDE BLACK | 
   100    | 215-277-5 | 
  
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Section 3 - Hazards Identification
 | 
EMERGENCY OVERVIEW
Appearance: black solid.
 Caution! May cause eye and skin irritation. May
cause respiratory and digestive tract irritation. Inhalation of
fumes may cause metal-fume fever. The toxicological properties of
this material have not been fully investigated.
Target Organs: None.
Potential Health Effects
     
Eye:
          May cause eye irritation.  Exposure to iron particles may cause
          toxic effects.
     
Skin:
          May cause skin irritation.
     
Ingestion:
          May cause gastrointestinal irritation with nausea, vomiting and
          diarrhea. The toxicological properties of this substance have not
          been fully investigated.
     
Inhalation:
          May cause respiratory tract irritation. Inhalation of fumes may
          cause metal fume fever, which is characterized by flu-like symptoms
          with metallic taste, fever, chills, cough, weakness, chest pain,
          muscle pain and increased white blood cell count. The toxicological
          properties of this substance have not been fully investigated.
     
Chronic:
          No information found.
  
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Section 4 - First Aid Measures
 | 
     
Eyes:
          Immediately flush eyes with plenty of water for at least 15 minutes,
          occasionally lifting the upper and lower eyelids. Get medical aid.
     
Skin:
          Flush skin with plenty of water for at least 15 minutes while
          removing contaminated clothing and shoes. Get medical aid if
          irritation develops or persists.
     
Ingestion:
          If victim is conscious and alert, give 2-4 cupfuls of milk or water.
          Get medical aid immediately.
     
Inhalation:
          Get medical aid immediately. Remove from exposure and move to fresh
          air immediately. If not breathing, give artificial respiration. If
          breathing is difficult, give oxygen.
     
Notes to Physician:
          No specific antidote exists.  Treat symptomatically and supportively.
  
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Section 5 - Fire Fighting Measures
 | 
     
General Information:
          As in any fire, wear a self-contained breathing apparatus in
          pressure-demand, MSHA/NIOSH (approved or equivalent), and full
          protective gear. Combustion generates toxic fumes.
     
Extinguishing Media:
          Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
                  Upper: Not available.
     
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
  
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Section 6 - Accidental Release Measures
 | 
     
General Information: Use proper personal protective equipment as indicated
                          in Section 8.
     
Spills/Leaks:
          Sweep up or absorb material, then place into a suitable clean, dry,
          closed container for disposal. Avoid generating dusty conditions.
  
    | 
Section 7 - Handling and Storage
 | 
     
Handling:
          Wash thoroughly after handling. Use with adequate ventilation.
          Minimize dust generation and accumulation. Avoid contact with skin
          and eyes. Keep container tightly closed. Avoid ingestion and
          inhalation.
     
Storage:
          Store in a cool, dry, well-ventilated area away from incompatible
          substances.
  
    | 
Section 8 - Exposure Controls, Personal Protection
 | 
     
Engineering Controls:
          Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
  | Chemical Name | 
    ACGIH | 
    NIOSH | 
    OSHA - Final PELs | 
| IRON OXIDE BLACK
 | 
none listed
 | 
none listed
 | 
none listed
 | 
     
OSHA Vacated PELs:
          IRON OXIDE BLACK:
             No OSHA Vacated PELs are listed for this chemical.
     
Personal Protective Equipment
                 
Eyes:
                       Wear appropriate protective eyeglasses or chemical
                       safety goggles as described by OSHA's eye and face
                       protection regulations in 29 CFR 1910.133 or European
                       Standard EN166.
                 
Skin:
                       Wear appropriate protective gloves to prevent skin
                       exposure.
             
Clothing:
                       Wear appropriate protective clothing to minimize
                       contact with skin.
          
Respirators:
                       Follow the OSHA respirator regulations found in 29
                       CFR 1910.134 or European Standard EN 149. Use a
                       NIOSH/MSHA or European Standard EN 149 approved
                       respirator if exposure limits are exceeded or if
                       irritation or other symptoms are experienced.
  
    | 
Section 9 - Physical and Chemical Properties
 | 
Physical State:  Solid
Appearance:      black
Odor:            none reported
pH:              Not available.
Vapor Pressure:  Not applicable.
Vapor Density:   Not applicable.
Evaporation Rate:Not applicable.
Viscosity:       Not available.
Boiling Point:   Not applicable.
Freezing/Melting Point:2892 deg F
Decomposition Temperature:Not available.
Solubility:      Insoluble in water.
Specific Gravity/Density:5.18 (water=1)
Molecular Formula:Fe3O4
Molecular Weight:231.5386
  
    | 
Section 10 - Stability and Reactivity
 | 
     
Chemical Stability:
          Stable under normal temperatures and pressures.
     
Conditions to Avoid:
          High temperatures, incompatible materials.
     
Incompatibilities with Other Materials:
          Aluminum, calcium hypochlorite, cesium carbide, chloroformates,
          ethylene oxide, peroxides.
     
Hazardous Decomposition Products:
          Irritating and toxic gases.
     
Hazardous Polymerization: Has not been reported
  
    | 
Section 11 - Toxicological Information
 | 
     
RTECS#:
     
CAS# 1317-61-9
unlisted.
     
LD50/LC50:
          Not available.
     
Carcinogenicity:
       CAS#    1317-61-9:
          Not listed by ACGIH, IARC, NTP, or CA Prop 65.
     
Epidemiology:
No information available.
     
Teratogenicity:
No information available.
     
Reproductive Effects:
No information available.
     
Mutagenicity:
Please refer to RTECS for specific information.
     
Neurotoxicity:
No information available.
     
Other Studies:
  
    | 
Section 12 - Ecological Information
 | 
Ecotoxicity:
          No data available.
          No information available.
Environmental:
          No information reported.
Physical:
          No information available.
Other:
          No information available.
  
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Section 13 - Disposal Considerations
 | 
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
  
    | 
Section 14 - Transport Information
 | 
  |        | 
    US DOT | 
    Canada TDG | 
| Shipping Name: | 
Please contact Fisher Scientific for shipping information | 
No information available. | 
| Hazard Class: | 
 | 
 | 
| UN Number: | 
 | 
 | 
| Packing Group: | 
 | 
 | 
  
    | 
Section 15 - Regulatory Information
 | 
 US FEDERAL
     
TSCA
     CAS# 1317-61-9 is listed on the TSCA inventory.
        
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
        
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
        
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
        
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
        
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
        
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
        
Section 313
     No chemicals are reportable under Section 313.
     
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
     
Clean Water Act:
     None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
     None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
     
OSHA:
     None of the chemicals in this product
are considered highly hazardous by OSHA.
 
STATE
          CAS#    1317-61-9 is not present on
     state lists from CA, PA, MN, MA, FL, or NJ.
 
California Prop 65
     
California No Significant Risk Level:
     None of the chemicals in this product are listed.
 
European/International Regulations
     European Labeling in Accordance with EC Directives
          Hazard Symbols:
      Not available.
          
Risk Phrases:
          
Safety Phrases:
   
WGK (Water Danger/Protection)
     CAS# 1317-61-9: 0
   Canada - DSL/NDSL
     CAS# 1317-61-9 is listed on Canada's DSL List.
   Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
   Canadian Ingredient Disclosure List
  
    | 
Section 16 - Additional Information
 | 
     MSDS Creation Date: 12/12/1997  
Revision #3 Date: 10/03/2005
     The information above is believed to be accurate and represents the best
     information currently available to us. However, we make no warranty of
     merchantability or any other warranty, express or implied, with respect to
     such information, and we assume no liability resulting from its use. Users
     should make their own investigations to determine the suitability of the
     information for their particular purposes. In no event shall Fisher be liable
     for any claims, losses, or damages of any third party or for lost profits
     or any special, indirect, incidental, consequential or exemplary
     damages, howsoever arising, even if Fisher has been advised of
     the possibility of such damages.