SHERWIN-WILLIAMS CO -- SHER-LINER STRIPING PAINT, 160-0006, HIGHWAY WHITE -- 8010-00N085167
===================== Product Identification ===================== Product ID:SHER-LINER STRIPING PAINT, 160-0006, HIGHWAY WHITE MSDS Date:11/01/1995 FSC:8010 NIIN:00N085167 === Responsible Party === Company Name:SHERWIN-WILLIAMS CO Address:101 PROSPECT AVE NW City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:216-566-2902 Emergency Phone Num:216-566-2917 CAGE:54636 === Contractor Identification === Company Name:SHERWIN-WILLIAMS CO THE Address:101 PROSPECT AVE NW Box:City:CLEVELAND State:OH ZIP:44115-1042 Country:US Phone:800-251-2486/216-566-2242 CAGE:54636 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE (PROPELLANT). VP:760. CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:BUTANE (PROPELLANT). VP:760. CAS:106-97-8 RTECS #:EJ4200000 Fraction by Wt: 10% OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:V.M. & P. NAPHTHA. VP:12. CAS:64742-89-8 Fraction by Wt: 3% OSHA PEL:300 PPM;400 PPM(MFR) ACGIH TLV:300 PPM (MFR) Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313). VP:7.1. CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 2% OSHA PEL:100 PPM ACGIH TLV:100 PPM;125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9. CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 13% OSHA PEL:100 PPM ACGIH TLV:100 PPM;150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA). VP:92. CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: 2% OSHA PEL:200 PPM, S ACGIH TLV:200 PPM;250 STEL, S EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETONE (SARA 313) (CERCLA). VP:180. CAS:67-64-1 RTECS #:AL3150000 Fraction by Wt: 16% OSHA PEL:1000 PPM ACGIH TLV:750 PPM;1000 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE). OSHA PEL:15 MG/M3; 5 MG/M3 RDUST (MFR). CAS:471-34-1 RTECS #:FF9335000 Fraction by Wt: 5% OSHA PEL:SEE INGREDIENT ACGIH TLV:10 MG/M3 (MFR) Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 Fraction by Wt: 3% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 17% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:BARIUM COMPOUND (CONTAINING 1.5% BARIUM) Fraction by Wt: 17% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT:WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL. WARNING:PROD CONTAINS CHEM(S) KNOWN TO THE STATE OF (ING 15) RTECS #:9999999ZZ Ingred Name:ING 15:CALIFORNIA TO CAUSE CANCER (CAL PROP 65). RTECS #:9999999ZZ Ingred Name:OTHER PREC:PROCS. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE COATINGS MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3(ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:(RESPIRABLE FRACTION). ADDITION OF REDUCERS/OTHER ADDITIVES TO THESE PRODS MAY SUBSTANTIALLY ALTER THE (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:COMPOSITION & HAZARDS OF THE PRODUCTS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF EXCESSIVE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MIST. REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, REPRO & CARDIO-V ASCULAR SYS. RATS EXPOS TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVEL LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE (SUPDAT) Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED. ======================= First Aid Measures ======================= First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST:SEEK MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:<0F,<-18C Lower Limits:0.7% Upper Limits:12.8% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. WASTE MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT) Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE & REMOVE W/INERT ABSORBENT. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DOL STOR CATEGORY-1A. CONTENTS ARE EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF IGNIT. CONSULT NFPA CODE . USE APPRVD BONDING & GROUNDING(ING 16) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING DRIED FILM, WEAR NIOSH APPRV D DUST/MIST RESP FOR DUST WHICH (SUPDAT) Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA) Protective Gloves:CHEMICAL RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . Work Hygienic Practices:WASH HANDS AFTER USING. Supplemental Safety and Health FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN. RESP PROT:MAY BE GENERATED FROM THIS PROD, UNDERLYING PAINT/ABRASIVE. VENT:1910.94, 1910.107, 1910.108. EFTS OF OVEREXP:NOT ATTAINABLE IN (ING 13) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:<325F,<163C Vapor Pres:SEE INGS Vapor Density:HVR/AIR Volatile Org Content %:56 Evaporation Rate & Reference:FASTER THAN ETHER Appearance and Odor:NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume:>75 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE KNOWN. Stability Condition to Avoid:NONE KNOWN. Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF METALS IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WASTE FROM THESE PRODUCTS MAY BE HAZARDOUS AS DEFINED UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBER. DO NOT INCIN. DEPRESSURIZE CNTNR. DISP O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.